Sodium chloride (NaCl) is used in IR spectroscopy in the 0.25–16 μm wavelength range. NaCl is a hygroscopic material therefore the optical components require storage in desiccatoror in sealed package with silica gel in a warm room and the polished surfaces must be protected from the moisture by exposing to only a dry atmosphere while using. Sodium chloride can be used to temperatures up to 400°C. The material is sensitive to thermal shock.
Application:
Product types:
- Plane-parallel windows and wedges
- Lenses
Specifications
Tab.1. Typical specification of NaCl optical components
| Specification |
Typical |
State-of-the-art |
| Sizes |
See table in the article Plane Windows and Wedged Windows |
Up to 100 mm |
| Diameter tolerance, mm |
+0/-0.25 |
RFQ |
| Thickness tolerance, mm |
±0.25 |
RFQ |
| Thickness matching, mm |
— |
RFQ |
| Surface quality, scr/dig |
60/40 |
RFQ |
| Surface flatness, λ @ 633nm per inch* |
2 |
RFQ |
| Parallelism (wedge tolerance) |
5 arc min |
RFQ |
| Coating |
none |
protecting |
| Packaging |
Typak® |
|
|
Transmission Spectrum

The measurements were carried out on Perkin Elmer Lambda-35 spectrophotometer and on BrukerVertex-70 Fourier-spectrometer.
Tab.2. Refractive index
| λ, µm |
n |
| 0.35 |
1.58 |
| 0.37 |
1.57 |
| 0.46 |
1.56 |
| 0.51 |
1.55 |
| 0.68 |
1.54 |
| 1.25 |
1.53 |
| 4.50 |
1.52 |
| 7.30 |
1.51 |
| 9.50 |
1.50 |
| 10.60 |
1.49 |
| 12.00 |
1.48 |
| 13.10 |
1.47 |
| 14.20 |
1.46 |
| 15.10 |
1.45 |
| 16.00 |
1.44 |
|
Tab.3. Optical properties
| Transmission range, microns |
0.25 – 16 |
| Colour |
Colourless |
| Reflection losses @ 11 µm (2 surfaces), % |
7.5 |
| Absorption coefficient, @ 3.8 µm, 10-4 cm-1 |
<0.0002 |
| Restrahlen peak, μm |
50.1 |
| dN/dT, 10-6/C |
-40.83 |
|
Tab.4. Physical and mechanical properties
| Class / Structure |
Cubic FCC, Fm3m, (100) cleavage |
| Density @300K, g/cm3 |
2.17 |
| Molecular Weight |
58.45 |
| Melting Point, °C |
801 |
| Thermal Conductivity @273K, W/(mxK) |
1.15 |
| Thermal Expansion @273K, 10-6/C |
44 |
| Hardness, Knoop with 200g indenter |
in (100) |
18.2 |
| in (110) |
15.2 |
| Specific Heat Capacity, J/(kg×K) |
854 |
| Debye temperature, K |
321 |
| Dielectric Constant for 106 Hz @300K |
5.9 |
| Bandgap, eV |
9.0 |
| Young Modulus (E), GPa |
39.98 |
| Shear Modulus (G), GPa |
12.61 |
| Bulk Modulus (K), GPa |
24.42 |
| Elastic Coefficient |
C11 = 48.7 C12 = 12.6 C44 = 12.75 |
| Apparent Elastic Limit, MPa |
2.4 |
| Poisson Ratio |
0.252 |
|
Tab.5. Chemical stability / Solubility
in water (at 0 оС) |
35.7 g/100cm3 hygroscopic |
| in acids |
insoluble in HCl |
| in organic solvents: |
|
| alcohol |
slightly soluble |
| glycerol |
soluble |
|
Please pay your attention that this article is for your information only. We do not supply NaCl in ingots as well as semi-finished products. Our standard products are polished parts.
For further information on our KCl optical components please see the following: Windows for IR-spectroscopy, Packaging or fill in our request form.